| Abstract: | The effects of comonomer composition on the curing kinetics of unsaturated polyester (UP) resins at 70–90°C were studied by differential scanning calorimetry (DSC) and infrared (IR) spectroscopy over the whole conversion range. One commercial UP resin, UP2660PF2, with cobalt promoter added and with 8.85 unsaturated C?C bonds per polyester molecule, was used. It was found that a marked shoulder in the initial DSC rate profile, rather than that reported after the peak of rate profile for low-temperature and high-temperature reactions, appeared when the molar ratio of styrene to polyester C?C bonds was greater than 1. With the initiator system accelerated by cobalt promoter, the formation rate of microgel particles would be enhanced at the early stage of reaction, as supported by the much higher conversion of polyester C?C bonds than that of styrene by IR spectroscopy. Those relatively greater number of microgel particles tended to facilitate the intramicrogel crosslinking reactions, which would be independently identified from the initial DSC rate profile as a shoulder. Consequently, the reaction mechanism was elucidated by decomposing the reaction rate profile into two individual profiles accounting for the intramicrogel dominated and the intermicrogel dominated crosslinking reactions, respectively. © 1993 John Wiley & Sons, Inc. |
