Conducting polymer coated carbon surfaces and biosensor applications |
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| Authors: | Murat Ates A. Sezai Sarac |
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| Affiliation: | 1. Department of Chemistry, Faculty of Arts and Sciences, Namik Kemal University, Namik Kemal Street, Number: 14, 59100 Tekirdag, Turkey;2. Department of Chemistry, Polymer Science and Technology, Istanbul Technical University, Maslak, 34469 Istanbul, Turkey |
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| Abstract: | This review article focuses on several approaches in the characterization and modification of carbon surfaces with electrocoated thin films which has been realized by recent progress in experimental methods. Electropolymerization and electrocopolymerization of π-conjugated polymers (pyrrole, carbazole, N-vinylcarbazole and aniline) onto carbon surfaces are reviewed with 348 references. Particular emphasis is placed on the recent nanoscale surface characterization techniques applied to the resulting electrocoated polymers onto carbon fibers (i.e., scanning electron microscopy (SEM), cyclic voltammetry (CV), X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), focused ion beam-secondary ion mass spectroscopy (FIB-SIMS), Fourier transformed infrared spectroscopy (reflectance-FTIR), and Raman spectroscopic measurements). |
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| Keywords: | AA, Ascorbic acid ACN, acetonitrile ACF, active carbon fiber AFM, atomic force microscopy ANI, aniline CF, carbon fiber CFME, carbon fiber microelectrode CH2Cl2, dichloromethane CNTs, carbon nanotubes CPE, carbon paste electrode CNS, central nervous system CV, cyclic voltammetry DA, dopamine DPV, differential pulse voltammetry DOQ, dopaminequinone ECMs, electrochromic materials ECMD, electrochemomechanical deformation ESR, electron spin resonance ETCZ, N-ethylcarbazole EQCM, electrochemical quartz crystal microbalance FSCV, fast scan cyclic voltammetry FTIR-ATR, Fourier transform infrared reflectance (attenuated-total reflection) spectroscopy FTO, fluorine tin oxide GCE, glassy carbon electrode GO, graphite oxide HER, hydrogen evolution reaction HTT, highest treatment temperature ITO, indium tin oxide MFB, medial forebrain bundle MPhPy, methoxy phenylpyrrole MWNTs, multi-walled carbon nanotubes NG, natural graphite NO, nitric oxide N-MPy, N-methylpyrrole PAN, polyacylonitrile p-AP, p-aminophenol Pt, platinum Pani, polyaniline PC, propylene carbonate pTsp, p-tolylsulfonyl pyrrole PVA, poly(vinyl acetate) PPy, polypyrrole PCz, polycarbazole P(MPhPy), poly(methoxy phenylpyrrole) P3MT, poly(3 methylthiophene) P(PhPy), poly(N-phenylpyrrole) P(NVCz), poly(N-vinylcarbazole) RMS, root mean square RRDE, rotating ring disk electrode RVC, reticulated vitreous carbon SEM, scanning electron microscopy SWNTs, single walled carbon nanotubes SDS, sodium dodecyl sulfate SCE, saturated calomel electrode TEAP, tetraethyl ammonium perchlorate TEM, transmission electron microscopy UA, uric acid UMEs, ultra-microelectrodes XRD, X-ray diffraction XPS, X-ray photoelectron spectroscopy |
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