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Equilibria in the gas system S-O-C between 550 and 1100°C
Authors:M C Pope  J H Woodhead  N Birks
Affiliation:(1) Research Laboratories, British Steel Corporation, Ladgate Lane, Middlesborough, England;(2) Department of Metallurgy, Sheffield University, England
Abstract:Equilibria in the S-O-C gas system have been calculated, for a variety of starting values of CO, CO2, and SO2 between 550–1100° C, assuming the existence of 10 gaseous species. It is shown that the species COS, SO3, CS, and SO may form in concentrations sufficiently high that values of sulfur and oxygen partial pressures, calculated from the initial values of CO, CO2, and SO2, are in error. Results are given for three sets of initial compositions and are available for 39 more.
Keywords:S-O-C equilibria  computer calculations  sulfur and oxygen partial pressure
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