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超细电纺纳米纤维的直接制备(英文)
引用本文:李文望,郑高峰,王翔,左文佳,张玉龙,李磊,孙道恒. 超细电纺纳米纤维的直接制备(英文)[J]. 纳米技术与精密工程, 2011, 9(6): 471-476
作者姓名:李文望  郑高峰  王翔  左文佳  张玉龙  李磊  孙道恒
作者单位:1. 厦门大学机电工程系,厦门 361005;厦门理工学院机械工程系,厦门 361005
2. 厦门大学机电工程系,厦门,361005
3. 厦门大学萨本栋微纳米技术研究中心,厦门,361005
4. 厦门大学材料科学与工程系,厦门,361005
基金项目:国家自然科学基金重点资助项目(51035002);国家自然科学基金资助项目(50875222)
摘    要:采用装配有疏水铜网的新型喷头研究了超细纳米纤维的制备.静电纺丝实现之前,首先对铜网进行了疏水处理,并将其安装于喷头前端.静电纺丝过程中,聚合物溶液由精密注射泵输送至喷头处.安装于喷头的铜网可将管道内的聚合物溶液分成多股细流从铜网网孔中流出.从铜网网孔流出的溶液细流受电场力作用被拉伸成多股独立射流,并从喷头携带走聚集的正电荷.受铜网表面疏水性和射流间电荷排斥力的影响,从铜网喷射出的多股射流都将保持其独立的轨迹而不会产生聚集.疏水铜网有利于减小纺丝射流的初始直径,并获得均匀的超细纳米纤维.利用新型的电纺丝喷头成功制备了直径20~80 nm的聚氧化乙烯(PEO)和聚乙烯醇(PVA)超细纳米纤维.实验结果表明,超细纳米纤维的直径随着电纺丝溶液浓度的增加而变大.

关 键 词:超细纳米纤维  静电纺丝  喷丝头  铜网  疏水处理

Direct Fabrication of Ultrafine Electrospinning Nanofiber
LI Wen-wang,ZHENG Gao-feng,WANG Xiang,ZUO Wen-jia,ZHANG Yu-long,LI Lei,SUN Dao-heng. Direct Fabrication of Ultrafine Electrospinning Nanofiber[J]. Nanotechnology and Precision Engineering, 2011, 9(6): 471-476
Authors:LI Wen-wang  ZHENG Gao-feng  WANG Xiang  ZUO Wen-jia  ZHANG Yu-long  LI Lei  SUN Dao-heng
Affiliation:LI Wen-wang1,2,ZHENG Gao-feng1,WANG Xiang1,ZUO Wen-jia1,ZHANG Yu-long3,LI Lei4,SUN Dao-heng1(1.Department of Mechanical and Electrical Engineering,Xiamen University,Xiamen 361005,China,2.Department of Mechanical Engineering,Xiamen University of Technology,3.Pen-Tung Sah Micro-Nano Technology Research Center,4.Department of Materials Science and Engineering,China)
Abstract:A novel spinneret assembled with Cu grid was presented in this paper to fabricate ultrafine nanofiber directly.Before electrospinning,hydrophobic treatment was performed on the Cu grid,which was then fixed at the front end of spinneret.During electrospinning,the polymer solution was transferred to the spinneret by the precise syringe pump.Through the holes in the Cu grid,polymer solution flow was divided into several smaller ones.The fine liquid flow from each hole of Cu grid was stretched into individual j...
Keywords:ultrafine nanofiber  electrospinning  spinneret  Cu grid  hydrophobic treatment  
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