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Piezoelectric and dielectric properties of Cr-doped PSN-PZN-PZT quaternary piezoelectric ceramics
作者姓名:SUNQingchi  WANGLifeng  LIUPing  NIEQiang
作者单位:[1]SchoolofMaterialsScienceandEngineering,TianjinUniversity,Tianjin300072,China [2]SchoolofChemicalEngineeringandTechnology,TianjinUniversity,Tianjin300072,China
摘    要:PSN-PZN-PZT x wt.%Cr2O3, x=0.0-0.9, were prepared by conventional mixed oxide techniques at sintering temperatures of 1220℃-1300℃ for 2 h. The effect of sintering temperature on the microstructure and the piezoelectric properties was investigated by XRD, SEM, and other conventional measurement. The result indicated that with temperature increasing, the valence of Cr ion from Cr^5 or Cr^6 changes into Cr^3 , and the piezoelectric properties turn hard. With increasing Cr2O3 content, the amount of rhombohedral phases increases and the morphotropic boundary phase is correspondingly shifts to rhombohedral phase. A uniform microstructure and excellent comprehensive properties were obtained at 1240℃ as the amount of Cr2O3 is 0.5 wt.%.

关 键 词:压电性质  介电性质  压电陶瓷  三氧化二铬  PSN-PZN-PZT  固态反应过程  烧结温度

Piezoelectric and dielectric properties of Cr-doped PSN-PZN-PZT quaternary piezoelectric ceramics
SUNQingchi WANGLifeng LIUPing NIEQiang.Piezoelectric and dielectric properties of Cr-doped PSN-PZN-PZT quaternary piezoelectric ceramics[J].Rare Metals,2005,24(2):185-189.
Authors:Sun Qingchi  Wang Lifeng  LIU Ping  Nie Qiang
Affiliation:1. School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China
2. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
Abstract:PSN-PZN-PZT + x wt.%Cr2O3, x = 0.0-0.9, were prepared by conventional mixed oxide techniques at sintering temperatures of 1220℃-1300℃ for 2 h. The effect of sintering temperature on the microstructure and the piezoelectric properties was investigated by XRD, SEM, and other conventional measurement. The result indicated that with temperature increasing, the valence of Cr ion from Cr5+ or Cr6+ changes into Cr3+, and the piezoelectric properties turn hard. With increasing Cr2O3 content, the amount of rhombohedral phases increases and the morphotropic boundary phase is correspondingly shifts to rhombohedral phase. A uniform microstructure and excellent comprehensive properties were obtained at 1240C as the amount of Cr2O3 is 0.5 wt.%.
Keywords:inorganic nonmetallic materials  PSN-PZN-PZT  conventional solid reaction process  Cr2O3 content  sintering temperature  piezoelectric properties
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