The solubility of hydrogen,deuterium and tritium in liquid lead-lithium alloys |
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Authors: | Michael Hoch |
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Affiliation: | Department of Materials Science and Metallurgical Engineering, University of Cincinnati, Cincinnati, OH 45221, USA |
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Abstract: | The solubility of H2, D2 and T2 in liquid Pb-Li alloys was calculated, as a function of composition and temperature, using the thermodynamic data of the binary systems. In the 17 at% Li alloy, at 600 K the D2 solubility is log K = ?4.20 ± 0.076, K in appm. torr?, that of H2 is ?4.125 ± 0.076, and that of T2 is ?4.244 ± 0.076. The calculated values give a much lower solubility than the experimental data. A ternary H-Li-Pb interaction term must be postulated to get agreement between experimental and calculated results. |
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