Quantitative luminescence mapping of Cu(In,Ga)Se2 thin‐film solar cells |
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Authors: | Amaury Delamarre,Myriam Paire,Jean‐Franç ois Guillemoles,Laurent Lombez |
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Abstract: | We investigate photoluminescence and electroluminescence (PL and EL) emission images from Cu(In,Ga)Se2‐based solar cells by means of a Hyperspectral Imager. Using the generalized Planck's law, maps of the effective quasi‐Fermi level splitting Δμeff in absolute values are obtained. A good agreement is found between the spatially averaged splitting in PL and the global open‐circuit voltage. However, from a local carrier transport discussion, we conclude that the equality does not hold locally. The spatial variations are rather attributed to local depth variations of the quasi‐Fermi level splitting due to material properties spatial fluctuations. By comparing PL and EL emissions, we discuss qualitatively the local effective lifetimes and collection efficiencies. Copyright © 2014 John Wiley & Sons, Ltd. |
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Keywords: | photoluminescence electroluminescence CIGS hyperspectral absolute intensity mapping |
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