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Solubility and electrochemical properties of chemically modified polyaniline‐gold/camphor sulfonic acid composites
Authors:C. Basavaraja  Gyu Ho Jung  Do Sung Huh
Abstract:Polyaniline nanocomposites encapsulating gold nanoparticles on camphor sulfonic acid (CSA) surface were prepared via the polymerization of aniline hydrochloride with different concentrations of CSA using HAuCl4 as oxidant. The synthesized composites were characterized by Fourier transform infrared spectroscopy and UV–visible spectroscopy. Surface morphology was studied by scanning electron microscopy and transmission electron microscopy. The embedded crystallinity of the composites was investigated by X‐ray diffraction analysis. The solubility of the nanocomposites was studied using water, N‐methyl‐2‐pyrrolidinone, chloroform, and dimethylformamide solvents. The room temperature direct current conductivity of the composites was also observed in solution state. Electrical property of the composites was examined using cyclic voltammetric measurements at room temperature. The fabricated polymer nanocomposites with better solubility in water and some organic solvents will have various applications in electrical devices and biosensors. POLYM. COMPOS., 36:245–252, 2015. © 2014 Society of Plastics Engineers
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