| 超支化聚酯的水溶性及交联剂应用 |
| |
| 引用本文： | 郝伟东,王立峰,刘立新. 超支化聚酯的水溶性及交联剂应用[J]. 化工科技, 2014, 22(5): 24-27 |
| |
| 作者姓名： | 郝伟东 王立峰 刘立新 |
| |
| 作者单位： | 1. 大庆油田有限责任公司 第五采油厂,黑龙江大庆,163513
2. 东北石油大学化学化工学院 石油与天然气化工省重点实验室,黑龙江大庆,163318 |
| |
| 摘 要： | 以顺丁烯二酸酐和甘油为原料合成了多官能团中间体,以季戊四醇为核分子进一步反应合成具有良好水溶性的端羟基超支化聚酯。当n(顺丁烯二酸酐)∶n(甘油)=1∶1,n(原料)∶n(季戊四醇)=100∶1和150∶1时,所得产物室温下具有良好水溶性。初步探索了超支化端羟基聚酯作为水性涂料交联剂,可使丙烯酸酯乳液性能明显提高。
|
| 关 键 词： | 超支化聚酯 水溶性 丙烯酸酯乳液 交联剂 |
Water solubility and application research of hyperbranched polyester |
| |
| Hao Weidong,Wang Lifeng,Liu Lixin. Water solubility and application research of hyperbranched polyester[J]. Science & Technology In Chemical Industry, 2014, 22(5): 24-27 |
| |
| Authors: | Hao Weidong Wang Lifeng Liu Lixin |
| |
| Affiliation: | Hao Weidong;Wang Lifeng;Liu Lixin;PetroChina Daqing Oilfield No.5 Oil Production Plant;Provincial Key Laboratory of Oil & Gas Chemical Technology,College of Chemistry & Chemical Engineering,Northeast Petroleum University; |
| |
| Abstract: | The intermediate with multi-functional groups was synthesized with maleic anhydride and glycerol,then the hyperbranched polyester was obtained by further reacted with pentaerythritol which acted as the nuclear molecular.When the molar ratio of maleic anhydride to glycerol was 1∶1,and the molar ratio of the intermediate to pentaerythritol was 100∶1and 150∶1,the hyperbranched polyester had good water solubility,and was used as crosslinking agent of acrylic ester latex,the performance of the latex was improved. |
| |
| Keywords: | Hyperbranched polyester Water solubility Acrylic ester latex Crosslinking agent |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
