| BC/TiCl4引发异丁烯活性阳离子聚合及其二嵌段共聚物的合成 |
| |
| 引用本文： | 李树新,郭文莉,金玉顺,李少毅.BC/TiCl4引发异丁烯活性阳离子聚合及其二嵌段共聚物的合成[J].北京石油化工学院学报,2004,12(1):12-15. |
| |
| 作者姓名： | 李树新 郭文莉 金玉顺 李少毅 |
| |
| 作者单位： | 北京石油化工学院化学工程系,北京,102617 |
| |
| 摘 要： | 研究了以苯甲酰氯(BC)/TiCl4为引发体系的异丁烯阳离子聚合.探讨了引发剂(BC)、共引发剂(TiCl4)、第三组分(TEA)对异丁烯阳离子聚合的影响规律,根据实验数据和GPC谱图的分析,确定了适宜的反应条件.在BC/TiCl4/TEA体系中,合成了PIB-PSt二嵌段共聚物.
|
| 关 键 词： | 异丁烯 阳离子聚合 二嵌段共聚物 |
| 修稿时间： | 2003年9月28日 |
Synthesis of IB Cationic Polymerization and PIB-b-PSt Diblock Copolymer by BC/TiCl4 |
| |
| Lis Shuxin,Guo Wenli,Jin Yushun,Li Shaoyi.Synthesis of IB Cationic Polymerization and PIB-b-PSt Diblock Copolymer by BC/TiCl4[J].Journal of Beijing Institute of Petro-Chemical Technology,2004,12(1):12-15. |
| |
| Authors: | Lis Shuxin Guo Wenli Jin Yushun Li Shaoyi |
| |
| Abstract: | The isobutylene cationic polymerization initiated by BC/TiCl4 was studied, the effects of initiator, co-initiator, electron donor on IB cationic polymerization was discussed, preferable reaction conditions were achieved by analyzing experimental data and GPC traces. PIB-b-PSt diblock copolymer was synthesized by sequentially adding IB and St into the BC/TiCl 4/TEA system. |
| |
| Keywords: | isobutylene cationic polymerization diblock copolymer |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
