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不同助交联剂在动态硫化PP/EPDM弹性体中的作用
引用本文:雷彩红.不同助交联剂在动态硫化PP/EPDM弹性体中的作用[J].中国塑料,2007,21(7):70-73.
作者姓名:雷彩红
作者单位:广东工业大学材料与能源学院,广东广州510006
摘    要:分析了不同的助交联剂对过氧化物硫化聚丙烯/乙烯-丙烯-二烯共聚物(EPDM)热塑性弹性体力学性能、流变性能、热稳定性能的影响,结果表明:不同的助交联剂均有提高凝胶含量和改善聚丙烯(PP)降解程度、提高力学性能的用途。其中,三羟甲基丙烷二烯丙基醚(TMPDE)作为过氧化物硫化PP/EPDM的助交联剂,相比三烯丙基异氰脲酸酯(TAIC)、邻苯二甲酸二烯丙酯(DAP)和三羟甲基丙烷三丙烯酸酯(TMPTA),所得制品综合力学性能优异,热稳定性能提高,流动性改善,微观结构均匀。

关 键 词:聚丙烯  乙烯-丙烯-二烯共聚物  热塑性弹性体  动态硫化  助交联剂
文章编号:1001-9278(2007)07-0070-04
修稿时间:2007-04-01

Effect of Co-agent on Properties of Dynamically Vulcanized PP/EPDM Thermoplastic Elastomers
LEI Cai-hong.Effect of Co-agent on Properties of Dynamically Vulcanized PP/EPDM Thermoplastic Elastomers[J].China Plastics,2007,21(7):70-73.
Authors:LEI Cai-hong
Affiliation:School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, China
Abstract:The effect of co-crosslinker on the physical, rheological and heat stability properties of peroxide dynamically vulcanized PP/EPDM elastomers was studied. It was showed that all of the co-crosslinker increased the gel content, inhibited the degradation of PP, and improved the mechanical properties of PP/EPDM. Compared among the systems using TMPTA, DAP, and TAIC, the one using TMPDE exhibited better mechanical properties, higher flow ability, and more uniform microstructure than the other two.
Keywords:polypropylene  ethylene-propylene-diene copolymer  thermoplastic elastomer  dynamic vul canization  co-agent
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