| ABS／纳米CaCO3复合材料流变性能的研究 |
| |
| 引用本文： | 张芳,程方亲,任长富.ABS／纳米CaCO3复合材料流变性能的研究[J].中国塑料,2007,21(10):52-56. |
| |
| 作者姓名： | 张芳 程方亲 任长富 |
| |
| 作者单位： | 安徽大学化学化工学院,安徽合肥230039 |
| |
| 基金项目： | 安徽省高校自然科学基金资助（2006KJ01B）;安徽省绿色高分子材料重点实验室资助 |
| |
| 摘 要： | 采用双螺杆挤出机，通过熔融共混工艺制备了丙烯腈-丁二烯-苯乙烯共聚物／纳米碳酸钙（ABS／nano-CaCO3）复合材料，利用转矩流变仪研究了其流变行为，探讨了nano-CaCO3用量、剪切速率和温度对复合材料黏度的影响。实验数据显示：ABS／nano-CaCO3熔体为假塑性流体，非牛顿指数n〈1；适量加入nano-CaCO3使复合体系熔体的n值增加，“柱塞流动”现象降低；在低剪切速率下，ABS／nano-CaCO3复合体系的熔体黏度较纯ABS熔体低；在高剪切速率下,复合体系的熔体黏度较纯ABS熔体高。
|
| 关 键 词： | 丙烯腈-丁二烯-苯乙烯共聚物 纳米碳酸钙 流变性能 表观黏度 |
| 文章编号： | 1001-9278（2007）10-0052-05 |
| 修稿时间： | 2007-06-08 |
Study on the Rheological Behavior of ABS/nano-CaCO3 Composites |
| |
| ZHANG Fang, CHENG Fang-qin, REN Chang-fu.Study on the Rheological Behavior of ABS/nano-CaCO3 Composites[J].China Plastics,2007,21(10):52-56. |
| |
| Authors: | ZHANG Fang CHENG Fang-qin REN Chang-fu |
| |
| Affiliation: | School of Chemistry and Chemical Engineering, Anhui University, Hefei 230039, China |
| |
| Abstract: | ABS/nano-CaCO3 composites were prepared by melt-blending in a twin screw extruder. The theological behavior of the composites was studied using a torque rheometer. The effects of the nano-CaCO3 content, shear rate, and temperature on the melt viscosity of the composites were discussed. The data showed that the melt of ABS/nano-CaCO3 composites was pseudoplastic, the inclusion of nano-CaCO3 decreased the tendency of mast and tuck flowing. |
| |
| Keywords: | acrylonitrile-butadiene-styrene copolymer nano-CaCO3 rheological behavior apparent viscosity |
| 本文献已被 维普 等数据库收录！ |
