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Nano-CaCO3 templated mesoporous carbon as anode material for Li-ion batteries
Authors:Bin Xu  Lu Shi  Xianwei Guo  Lu Peng  Zhaoxiang Wang  Shi Chen  Gaoping Cao  Feng Wu  Yusheng Yang
Affiliation:aResearch Institute of Chemical Defense, Beijing 100191, China;bBeijing Key Laboratory of Environmental Science and Engineering, Beijing Institute of Technology, Beijing 100081, China;cInstitute of Physics, Chinese Academy of Sciences, Beijing 100190, China
Abstract:Mesoporous hard carbon is obtained by pyrolyzing a mixture of sucrose and nanoscaled calcium carbonate (CaCO3) particles. The microstructure of the carbon is characterized by N2 adsorption/desorption, Hg porosimetry, field-emission scanning electron microscopy (FESEM), X-ray diffraction (XRD) and Raman spectroscopy. The electrochemical performances of the carbon as an anode material for lithium ion batteries are evaluated by galvanostatic charge/discharge and cyclic voltammetry tests. It is shown that this mesoporous carbon possesses high capacity, good cycling performance and rate capability, indicating the promising application of nano-CaCO3 particle as template in massive fabrication of mesoporous carbon anode materials for lithium ion batteries.
Keywords:Lithium ion battery   Mesoporous carbon   Capacity   Cycle performance
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