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多壁碳纳米管对有机物的吸附研究
引用本文:贺金梅,黄一峰,黄玉东,吴亚东,孙德智.多壁碳纳米管对有机物的吸附研究[J].化学与粘合,2010,32(1):1-4.
作者姓名:贺金梅  黄一峰  黄玉东  吴亚东  孙德智
作者单位:贺金梅,HE Jin-mei(哈尔滨工业大学化工学院,哈尔滨,黑龙江,150001;哈尔滨工业大学市政环境学院,哈尔滨,黑龙江,150090);黄一峰,黄玉东,吴亚东,HUANG Yi-feng,HUANG Yu-dong,WU Ya-dong(哈尔滨工业大学化工学院,哈尔滨,黑龙江,150001);孙德智,SUN De-zhi(哈尔滨工业大学市政环境学院,哈尔滨,黑龙江,150090) 
摘    要:研究多壁碳纳米管(MWNTs)对水中有机物间苯二酚的吸附。分别讨论了不同的吸附参数(如温度、时间、pH)条件下,碳纳米管对间苯二酚吸附量的变化情况,并采用Langmuir和Freundlich模型对MWNTs的吸附等温线进行拟合。结果表明:MWNTs的吸附平衡时间为1h;MWNTs吸附是一个自发的放热过程,低温对其吸附有利;当溶液的pH值在4附近时,MWNTs对间苯二酚的吸附量达到最大;MWNTs对间苯二酚的吸附符合Freundlich和Langmuir等温模型。

关 键 词:MWNTs  吸附  温度  pH  时间

Adsorption of Benzenediol from Aqueous Solution by MWNTs
HE Jin-mei,HUANG Yi-feng,HUANG Yu-dong,WU Ya-dong,SUN De-zhi.Adsorption of Benzenediol from Aqueous Solution by MWNTs[J].Chemistry and Adhesion,2010,32(1):1-4.
Authors:HE Jin-mei  HUANG Yi-feng  HUANG Yu-dong  WU Ya-dong  SUN De-zhi
Affiliation:1. College of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin 150001, China; 2. College of Municipal and Environmental Engineering, Harbin Institute of Technology, Harbin 150090, China)
Abstract:The multi-walled carbon nanotubes (MWNTs) were used as adsorbent to remove 1,3-benzenediol from water. The influence of variation of time, temperature and pH on the adsorption quantity of 1,3-benzenediol in water was analyzed. The adsorption of MWNTs was fitted separately utilizing Langmuir and Freundlieh models. The results showed that the adsorption balance time of MWNTs was 1 hour; the adsorption of MWNTs was spontaneous and heat released, hypothermia was beneficial to adsorption; when the pH was around 4, the adsorption quantity reached the top. The experimental data fit Langrnuir isotherm model better than Freundlieh one.
Keywords:MWNTs  pH
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