| 钛硅分子筛失活与再生的研究进展 |
| |
| 引用本文： | 王梅正,林民,朱斌. 钛硅分子筛失活与再生的研究进展[J]. 化工进展, 2007, 26(9): 1258-1262 |
| |
| 作者姓名： | 王梅正 林民 朱斌 |
| |
| 作者单位： | 中国石化青岛石化公司,山东,青岛,266043;中国石化石油化工科学研究院,北京,100083 |
| |
| 基金项目： | 国家“973”资助项目(No.2006CB202508) |
| |
| 摘 要： | 介绍了在烯烃环氧化、环己酮氨肟化、苯酚羟基化等催化氧化反应中钛硅分子筛失活的研究现状,分析了反应副产物堵孔是催化剂失活的主要原因,同时钛流失或硅溶解也是导致催化剂失活的原因之一。总结了钛硅分子筛目前采用的主要再生方法,简述了不同再生过程对催化剂结构与性能的影响。展望了钛硅分子筛再生研究的发展方向。
|
| 关 键 词： | 钛硅分子筛 失活 再生 |
| 文章编号： | 1000-6613（2007）09-1258-05 |
| 收稿时间： | 2007-06-15 |
| 修稿时间： | 2007-07-06 |
Advances in study of deactivation and regeneration of titanium silicalite |
| |
| WANG meizheng,LIN Min,ZHU Bin. Advances in study of deactivation and regeneration of titanium silicalite[J]. Chemical Industry and Engineering Progress, 2007, 26(9): 1258-1262 |
| |
| Authors: | WANG meizheng LIN Min ZHU Bin |
| |
| Affiliation: | 1 Qingdao Petrochemical Company, SINOPEC, Qingdao 266043, Shandong, China; 2 Research Institute of Petroleum Processing, SINOPEC, Beijing 100083, China |
| |
| Abstract: | The present status of deactivation and regeneration of titanium silicalite in main catalytic oxidation reactions,such as alkene epoxidation,cyclohexanone ammoxidation,phenol hydroxylation, etc. is reviewed. Pore blocking by reaction byproducts is the main reason for catalyst deactivation,and titanium leaching or silica dissolution is another reason.The present regeneration methods are summarized,and their effects on zeolite structure and catalytic performance are also presented.The research prospect of regeneration of titanium silicalite is discussed. |
| |
| Keywords: | titanium silicalite deactivation regeneration |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
