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膨胀石墨的孔隙结构-中国国家自然科学基金和日本学术振兴会联合研究项目报道
引用本文:稻垣道夫,丰田义雄,康飞宇,郑永平,沈万慈. 膨胀石墨的孔隙结构-中国国家自然科学基金和日本学术振兴会联合研究项目报道[J]. 新型炭材料, 2003, 18(4): 241-249
作者姓名:稻垣道夫  丰田义雄  康飞宇  郑永平  沈万慈
作者单位:1. 爱知工业大学,丰田市,470-0392,日本;清华大学,材料科学与工程学院,北京,100084
2. 国立福井工学院,Sabae,916-8507,日本
3. 清华大学,材料科学与工程学院,北京,100084
基金项目:中国国家自然科学基金 (50 1 72 0 2 7),中国国家基金委与日本学术振兴会的联合项目 (JSPSNSFC6 0 2 1 )~~
摘    要:通过对膨胀石墨膨化容积,石墨蠕虫之间和内部孔隙尺寸的测定,详细研究了膨胀石墨的孔结构,建立了一些估测孔结构的新技术;为了研究膨胀石墨的孔结构,发展了一些测量新技术:包括石腊浸渍法,将石墨蠕虫浸渍在液态石蜡中,石蜡就会填充石墨间的大孔隙,通过断裂方法还可以看到蠕虫内部孔隙,这些方法均需要借助图像处理技术。本论文第一部分分析了市售膨胀石墨的孔隙结构,第二和第三部分分别讨论了胀化温度和插层剂对孔结构的一些影响。

关 键 词:膨胀石墨 孔隙结构 图像处理 膨化程度 孔隙尺寸 胀化温度 插层剂

Pore structure of exfoliated graphite- A report on a joint research project under the scientific cooperation program between NSFC and JSPS
Michio Inagaki. Pore structure of exfoliated graphite- A report on a joint research project under the scientific cooperation program between NSFC and JSPS[J]. New Carbon Materials, 2003, 18(4): 241-249
Authors:Michio Inagaki
Affiliation:Michio Inagaki~
Abstract:The pore structure of exfoliated graphite was discussed on the basis of exfoliation volume, and size determination of pores among and inside the worm-like particles. In order to evaluate pore structures, new techniques were developed, which included a paraffin impregnation method for filling large spaces between the particles and fracturing across the worm-like particles for pores inside the particles, both being assisted by an image processing technique. In the first part of the present review, the pore structure of a commercially available exfoliated graphite was determined. In the second and third parts, the effects of exfoliation temperature and intercalate content are respectively discussed.
Keywords:Exfoliated graphite  Pore structure  Image processing  Exfoliation volume  Pore size
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