Biosynthesis of PP-V, a monascorubramine homologue, by Penicillium sp. AZ |
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| Authors: | Jun Ogihara Jun Kato Kunio Oishi Yoshinori Fujimoto |
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| Affiliation: | a Department of Agricultural Biological Chemistry, College of Bioresource Sciences, Nihon University, Kameino, Fujisawa, Kanagawa 252-8510, Japan;b Department of Chemistry and Materials Science, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8551, Japan |
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| Abstract: | The biosynthetic pathway of PP-V, a new monascorubramine homologue, was elucidated by 13C-labeling studies. The [1-13C] of acetate was incorporated into 2-, 3a-, 4a-, 6-, 8-, 9-, 11-, 13-, 15-, 17-, and 19-Cs of PP-V, and the [2-13C], into 3-, 4-, 5-, 8a-, 9a-, 10-, 12-, 14-, 16-, 18-, and 20-Cs. These incorporation patterns coincide with those reported in the biosynthesis of a Monascus azaphilone pigment, monascorubrin. |
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| Keywords: | Monascus Penicillium pigment azaphilone 13C-acetate |
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