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燃烧催化剂对EMCDB推进剂交联固化反应的催化作用
引用本文:刘春,李笑江,蔡炳源,安芳延.燃烧催化剂对EMCDB推进剂交联固化反应的催化作用[J].火炸药学报,2002,25(2):42-44.
作者姓名:刘春  李笑江  蔡炳源  安芳延
作者单位:西安近代化学研究所,陕西,西安,710065
摘    要:设计了一种研究燃烧催化剂对EMCDB推进剂交联固化反应催化作用的实验方法,比较了十多种铅盐、铜盐对交联固化反应催化活性的强弱,筛选出了可用作粒铸EMCDB推进剂燃烧催化剂的铅盐、铜盐。实验结果表明,某些铅盐对交联固化反应有较强的催化加速作用,铜盐和炭黑对交 联固化反应没有明显的催化加速作用,只有对交联固化反应催化加速作用很小的铅盐才能用作EMCDB推进的燃料催化剂。

关 键 词:燃烧催化剂  EMCDB推进剂  交联固化反应  双基推进剂
文章编号:1007-7812(2002)02-0042-03
修稿时间:2001年7月12日

Study on Curing Catalysis of Combustion Catalyst for EMCDB Propellant
LIU Chun,LI Xiao jiang,CAI Bing yuan,AN Fang yan.Study on Curing Catalysis of Combustion Catalyst for EMCDB Propellant[J].Chinese Journal of Explosives & Propellants,2002,25(2):42-44.
Authors:LIU Chun  LI Xiao jiang  CAI Bing yuan  AN Fang yan
Abstract:The experiment, applied to study the curing catalysis of combustion catalysis for polyurethane EMCDB propellant, was designed, the catalytic activity of eight Pb salts and four Cu salts was compared, the Pb salts and Cu-salts, which could be used as combustion catalyst ingredient of EMCDB propellant, were selected. Experimental results showed that some Pb salts had stronger catalytic activity to the cross linking reaction, almost all Cu salts and carbon black had no catalytic activity, only these Pb salts, which had weaker catalytic activity, could be used as the combustion catalyst ingredient of EMCDB propellant.
Keywords:EMCDB propellant  combustion catalyst  cross linking reaction
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