Complexation of Titanium Alkoxides with Cis-2-butene-1,4-diol and Hydrolysis of Their Products |
| |
| Authors: | Asgar Kayan |
| |
| Affiliation: | (1) Department of Chemistry, Kocaeli University, Iacute;zmit, Turkey |
| |
| Abstract: | Reaction of Ti(OEt)4 and Ti(OBun)4 with cis-2-butene-1,4-diol (B.diol-2H) in 1:1 molar ratio was studied at room temperature using the sol-gel process. 13C{1H}- and 1H-NMR data showed that all the B.diol-2H completely reacted with both titanium alkoxides. Each of the products was hydrolyzed by water. The new hydrolyzed products were characterized by 13C- and 1H-NMR spectroscopy and Karl–Fischer Titration. Thermogravimetric and differential thermal analyses (TGA-DTA) of the hydrolyzed-products were also studied. |
| |
| Keywords: | Sol-gel titanium alkoxides cis-2-butene-1,4-diol hydrolysis of metal alkoxides |
| 本文献已被 SpringerLink 等数据库收录！ |
|
