| 无皂乳液制备小微球集合型P(AMPS-MMA)微球 |
| |
| 引用本文： | 王艳丽,谭德新,张明旭,张彬. 无皂乳液制备小微球集合型P(AMPS-MMA)微球[J]. 高分子材料科学与工程, 2010, 0(4): 149-152 |
| |
| 作者姓名： | 王艳丽 谭德新 张明旭 张彬 |
| |
| 作者单位： | 安徽理工大学材料科学与工程学院;安徽理工大学化学工程学院; |
| |
| 基金项目： | 安徽省高校自然科学基金资助项目(KJ2009B054Z,KJ2009B120Z) |
| |
| 摘 要： | 用2-丙烯酰胺基-2-甲基丙磺酸(AMPS)作为功能单体与甲基丙烯酸甲酯(MMA)进行无皂乳液共聚合,得到了小微球集合型P(AMPS-MMA)微球。用红外光谱(FT-IR)、热性能分析(TG-DSC)和扫描电镜(SEM)等技术对样品进行表征,并采用表面张力法测得AMPS的临界胶束浓度(CMC)为0.072mol/L;通过探讨AMPS用量对反应体系的影响研究了聚合反应机理。结果表明,微球的Tg为170℃左右,平均粒径大约在20μm,呈单分散性,每个微球都由很小的微球集合而成,小微球的粒径大约在0.1μm。
|
| 关 键 词： | 小微球集合型微球 无皂乳液聚合 2-丙烯酰胺基-2-甲基丙磺酸 甲基丙烯酸甲酯 临界胶束浓度 |
Preparation and Characterization of P(AMPS-MMA) Fine Particles Clustered Microspheres via Emulsifier-Free Emulsion Polymerization |
| |
| WANG Yan-li,TAN De-xin,ZHANG Ming-xu,ZHANG Bin. Preparation and Characterization of P(AMPS-MMA) Fine Particles Clustered Microspheres via Emulsifier-Free Emulsion Polymerization[J]. Polymer Materials Science & Engineering, 2010, 0(4): 149-152 |
| |
| Authors: | WANG Yan-li TAN De-xin ZHANG Ming-xu ZHANG Bin |
| |
| Affiliation: | 1. Institute of Materials Science and Engineering;2. Institute of Chemical Engineering;Anhui University of Science and Technology;Huainan 232001;China |
| |
| Abstract: | The P(AMPS-MMA) fine particles clustered microspheres were synthesized via emulsifier-free emulsion polymerization with methyl methacrylate(MMA) and a functional monomer of 2-acrylamido-2-methylpropanesulfonic acid(AMPS). The samples were characterized by Fourier transform infrared spectrum(FT-IR),thermogravimetric analysis-differential scanning calorimetry(TG-DSC) and scanning electron microscope (SEM),and the critical micelle concentration(CMC) of AMPS obtained by surface tension measurement was 0.072 mol... |
| |
| Keywords: | fine particles clustered microspheres emulsifier-free emulsion polymerization 2-acrylamido-2-methylpropanesulfonic acid methyl methacrylate critical micelle concentration |
| 本文献已被 CNKI 等数据库收录！ |
