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Li4Ti5O12 hollow microspheres assembled by nanosheets as an anode material for high-rate lithium ion batteries
Authors:Yufeng Tang   Li Yang   Shaohua Fang  Zheng Qiu
Affiliation:aSchool of Chemistry and Chemical Technology, Shanghai Jiaotong University, No. 800 Dongchuan Road, Shanghai 200240, PR China
Abstract:In this paper, Li4Ti5O12 (LTO) hollow microspheres with the shell consisting of nanosheets have been synthesized via a hydrothermal route and following calcination. Because of the favorable transport properties of this hollow structure, it is the rate performance at high current densities which is exceptional. When the LTO hollow microspheres were used as the anode material in lithium ion battery, they exhibited superior rate performance and high capacity even at a very high rate (131 mAh g−1 at 50 C).
Keywords:Hierarchical structures   Self-assembly   Lithium titanate   High rate   Lithium ion battery
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