| 新型环氧端基聚芳醚砜的合成及表征 |
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| 引用本文： | 宣英男,蹇锡高,徐志勇,周庆兵. 新型环氧端基聚芳醚砜的合成及表征[J]. 高分子材料科学与工程, 2001, 17(1): 57-59 |
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| 作者姓名： | 宣英男 蹇锡高 徐志勇 周庆兵 |
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| 作者单位： | 大连理工大学化工学院高分子材料系 |
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| 基金项目： | 国家“九·五”重点科技攻关项目!(97- 5 6 4- 0 1- 0 7)部分工作 |
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| 摘 要： | 以４，４′－二氯二苯砜和４－（４－羟基苯基）－２，３－二氮杂萘-1-酮为原料，经亲核取代逐步聚合反应制分子主链中含二氮杂萘酮结构的聚芳醚砜低聚物（ＰＰＥＳ），然后与环氧氯丙烷反应制得所需分子量的含环氧端基的聚代醚砜（Ｅ－ＰＰＥＳ）。用ＦＴ－ＩＲ和^1H-NMR表达了分子链结构，考察了不同的反应温度、反应时间和反应单体配比对环氧化效果的影响，并测试了聚合物的溶解性能。
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| 关 键 词： | 环氧端基 聚芳醚砜 合成 表征 二氮杂萘酮 结构 |
| 文章编号： | 1000-7555(2001)01-0057-03 |
| 修稿时间： | 1999-05-07 |
SYNTHESIS AND CHARACTERIZATION OF A NOVEL EPOXY-TERMINATED POLY(ARYL ETHER SULFONE) |
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| XUAN Ying-nan,JIAN Xi-gao,XU Zhi-yong,ZHOU Qing-bing. SYNTHESIS AND CHARACTERIZATION OF A NOVEL EPOXY-TERMINATED POLY(ARYL ETHER SULFONE)[J]. Polymer Materials Science & Engineering, 2001, 17(1): 57-59 |
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| Authors: | XUAN Ying-nan JIAN Xi-gao XU Zhi-yong ZHOU Qing-bing |
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| Abstract: | A novel epoxy-terminated polyarylethersulfone(E-PPES) was synthesized by reaction of epichlorohydrin with PPES oligomer prepared by condensation of 4,4′-dichlorobenzophensulfone(DCDBS) with 4-(4-hydroxyphenyl)-2,3-phthalazine-1-one at non-eqular. E-PPES was characterized by FT-IR and 1H-NMR spectra, the effects of different conditions on epoxy reaction were studied, solubility of E-PPES samples were also measured. |
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| Keywords: | epoxy terminated poly(aryl ether sulfone) synthesL |
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