| 氢初压对渣油加氢产物胶体稳定性的影响及原因分析 |
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| 引用本文： | 于双林,张龙力,杨朝合,山红红.氢初压对渣油加氢产物胶体稳定性的影响及原因分析[J].石化技术与应用,2010,28(2). |
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| 作者姓名： | 于双林 张龙力 杨朝合 山红红 |
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| 作者单位： | 中国石油大学(华东)重质油国家重点实验室,山东,青岛,266555 |
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| 基金项目： | 国家重点基础研究发展计划(973计划,项目编号:2006CB202505);;国家自然科学基金(项目编号:20506017;20776160) |
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| 摘 要： | 在高温高压反应釜内,使用工业加氢转化催化剂对绥中36-1常压渣油进行了加氢反应,考察了氢初压对产物胶体稳定性的影响,并从产物的四组分组成、数均相对分子质量及胶质、沥青质的平均结构等方面对产生影响的原因进行了分析。结果表明,随着氢初压的升高,产物的稳定性先改善后略变差,其稳定性的改善可降低焦炭收率;产物的四组分中饱和分的含量增大,芳香分、胶质的含量变化不大,沥青质含量降低;芳香分、胶质的相对分子质量先增大后减小,沥青质的相对分子质量逐渐减小;胶质、沥青质的H/C原子比先增大后减小,芳香碳分率先降低后增大,二者结构性质的改变决定了产物胶体稳定性的变化趋势。
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| 关 键 词： | 氢初压 渣油 渣油加氢转化 胶体稳定性 沥青质 胶质 化学结构 |
Effects of hydrogen initial pressure on the colloidal stability of hydrotreated residuum |
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| Yu Shuanglin,Zhang Longli,Yang Chaohe,Shan Honghong.Effects of hydrogen initial pressure on the colloidal stability of hydrotreated residuum[J].Petrochemical Technology & Application,2010,28(2). |
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| Authors: | Yu Shuanglin Zhang Longli Yang Chaohe Shan Honghong |
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| Affiliation: | State Key Laboratory of Heavy Oil Processing;China University of Petroleum;Qingdao 266555;China |
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| Abstract: | Suizhong 36-1 atmospheric residuum was hydrotreated in an autoclave at high temperature using industrial hydroconversion catalyst,the effects of hydrogen initial pressure on the colloidal stability of product oil were investigated,and the reasons were analyzed from several parameters including the SARA composition,their mean relative molecular mass and the average structure parameters of gum and asphaltene.The results showed that the colloidal stability of product oil increased first and then reduced a litt... |
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| Keywords: | hydrogen initial pressure residuum residuum hydroconversion colloidal stability asphaltene gum chemical structure |
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