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反渗透处理煤层气产出水中试示范及其控制模型研究(英文)
引用本文:钱智,刘新春,余志晟,张洪勋,琚宜文.反渗透处理煤层气产出水中试示范及其控制模型研究(英文)[J].中国化学工程学报,2012,20(2):302-311.
作者姓名:钱智  刘新春  余志晟  张洪勋  琚宜文
作者单位:1. College of Resources and Environment, Graduate University of Chinese Academy of Sciences, Beijing 100049, China;2. Earth College, Graduate University of Chinese Academy of Sciences, Beijing 100049, China
基金项目:Supported by the National Basic Research Program of China(2011ZX05060-005;2009ZX05039-003);the National Natural Science Foundation of China(21106176);the President Fund of GUCAS(Y15101JY00);the National Science Foundation for Post-doctoral Scientists of China(20110490627)
摘    要:This study presents the first demonstration project in China for treatment of coal-bed methane(CBM) co-produced water and recycling.The work aims to provide a research and innovation base for solving the pollution problem of CBM extraction water.The reverse osmosis(RO) unit is applied to the treatment of CBM co-produced water.The results indicate that system operation is stable,the removal efficiency of the total dissolved solids(TDS) is as high as 97.98%,and Fe,Mn,and F-are almost completely removed.There is no suspended solids(SS) detected in the treated water.Furthermore,a model for the RO membrane separation process is developed to describe the quantitative relationship between key physical quantities-membrane length,flow velocity,salt concentration,driving pressure and water recovery rate,and the water recovery restriction equation based on mass balance is developed.This model provides a theoretical support for the RO system design and optimization.The TDS in the CBM co-produced water are removed to meet the "drinking water standards" and "groundwater quality standards" of China and can be used as drinking water,irrigation water,and livestock watering.In addition,the cost for treatment of CBM co-produced water is assessed,and the RO technology is an efficient and cost-effective treatment method to remove pollutants.

关 键 词:coal-bed  methane  co-produced  water  high  salt  pretreatment  process  mass  balance  reverse  osmosis  
收稿时间:2012-01-06

A Pilot-scale Demonstration of Reverse Osmosis Unit for Treatment of Coal-bed Methane Co-produced Water and Its Modeling
QIAN Zhi,LIU Xin-Chun,YU Zhi-Sheng,ZHANG Hong-Xun,J&#,Yi-Wen.A Pilot-scale Demonstration of Reverse Osmosis Unit for Treatment of Coal-bed Methane Co-produced Water and Its Modeling[J].Chinese Journal of Chemical Engineering,2012,20(2):302-311.
Authors:QIAN Zhi  LIU Xin-Chun  YU Zhi-Sheng  ZHANG Hong-Xun  J&#  Yi-Wen
Affiliation:1. College of Resources and Environment, Graduate University of Chinese Academy of Sciences, Beijing 100049, China;2. Earth College, Graduate University of Chinese Academy of Sciences, Beijing 100049, China
Abstract:This study presents the first demonstration project in China for treatment of coal-bed methane(CBM) co-produced water and recycling.The work aims to provide a research and innovation base for solving the pollution problem of CBM extraction water.The reverse osmosis(RO) unit is applied to the treatment of CBM co-produced water.The results indicate that system operation is stable,the removal efficiency of the total dissolved solids(TDS) is as high as 97.98%,and Fe,Mn,and F-are almost completely removed.There is no suspended solids(SS) detected in the treated water.Furthermore,a model for the RO membrane separation process is developed to describe the quantitative relationship between key physical quantities—membrane length,flow velocity,salt concentration,driving pressure and water recovery rate,and the water recovery restriction equation based on mass balance is developed.This model provides a theoretical support for the RO system design and optimization.The TDS in the CBM co-produced water are removed to meet the "drinking water standards" and "groundwater quality standards" of China and can be used as drinking water,irrigation water,and livestock watering.In addition,the cost for treatment of CBM co-produced water is assessed,and the RO technology is an efficient and cost-effective treatment method to remove pollutants.
Keywords:coal-bed methane co-produced water  high salt  pretreatment process  mass balance  reverse osmosis
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