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超声波/零价铁协同降解硝基苯的机理研究
引用本文:李天鹏. 超声波/零价铁协同降解硝基苯的机理研究[J]. 工业用水与废水, 2011, 42(3): 28-31
作者姓名:李天鹏
作者单位:浙江育英职业技术学院信息技术与应用系,杭州,310018
摘    要:对超声波/零价铁协同降解硝基苯的作用机理进行了研究.结果表明,超声波与零价铁联用时有明显的协同效应.超声辐照有利于铁屑转化为Fe2+,并进一步氧化为Fe3+,不规整铁屑对超声空化有促进作用,在超声波/零价铁体系中存在Fenton反应,通过产生大量的·OH降解硝基苯,该氧化过程是硝基苯降解的主要途径之一.

关 键 词:超声波  铁屑  硝基苯  ·OH

Mechanism of nitrobenzene degradation by ultrasound/zero-valent iron system
LI Tian-peng. Mechanism of nitrobenzene degradation by ultrasound/zero-valent iron system[J]. Industrial Water & Wastewater, 2011, 42(3): 28-31
Authors:LI Tian-peng
Affiliation:LI Tian-peng(Department of Information Technology and Applications,Zhejiang Yuying College of Vocational Technology,Hangzhou 310018,China)
Abstract:The mechanism of nitrobenzene degradation by ultrasound/aero-valent iron system was studied.The results showed that,ultrasound and zero-valent iron had obvious synergistic effect when they were used combinedly.Ultrasound irradiation could help convert iron scrap into Fe2+ and further oxidized it to Fe3+,meanwhile,irregular iron scrap could promote ultrasonic cavitation.As Fenton reaction existed in the ultrasound/zero-valent iron system,large amount of ·OH was produced,which could degrade nitrobenzene.The above oxidation process was one of the main ways for nitrobenzene degradation.
Keywords:ultrasound  iron scrap  nitrobenzene  ·OH
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