| N,N-、N,P-配体镍络合物催化乙烯聚合研究进展 |
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| 引用本文： | 张成,魏凯,许华.N,N-、N,P-配体镍络合物催化乙烯聚合研究进展[J].广州化工,2011,39(7):19-22. |
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| 作者姓名： | 张成 魏凯 许华 |
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| 作者单位： | 1. 北京师范大学珠海分校工程技术学院,广东,珠海,519087
2. 中国石油兰州石化乙烯厂,甘肃,兰州,730060 |
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| 摘 要： | 综述了以后过渡金属镍络合物为代表的,螯合N,N-、N,P-配体为催化剂催化烯烃聚合研究内容。对催化活性以及产物结构的影响进行了讨论,指出含N,N-、N,P-配体螯合的金属镍络合物催化剂催化乙烯聚合在这一领域的优势。
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| 关 键 词： | 配体 催化剂 有机金属镍络合物 乙烯 |
An Overview on the Polymerization of Ethylene Catalyzed by Complexes of Nickel Supported by N, N - and N, P - Ligands |
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| ZHANG Cheng,WEI Kai,XU Hua.An Overview on the Polymerization of Ethylene Catalyzed by Complexes of Nickel Supported by N, N - and N, P - Ligands[J].GuangZhou Chemical Industry and Technology,2011,39(7):19-22. |
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| Authors: | ZHANG Cheng WEI Kai XU Hua |
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| Affiliation: | 1 School of Engineering Technology,Beijing Normal University,Guangdong Zhuhai 519087;2 PetroChina Lanzhou Petrochemical Company,Gansu Lanzhou 730060,China) |
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| Abstract: | Progresses in catalytic polymerization of ethylene with nickel complexes of typical late-transition metal complexes bearing bidentate N,N-and N,P-ligands were reviewed.The effect of ligand on activity and the polymer structure were discussed.The advantage of the nickel ethylene polymerisation catalysts bearing bidentate N,N-and N,P-ligands in this field was discussed. |
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| Keywords: | ligands catalysts nickel complexes ethylene |
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