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现代二氧化氯制备技术
引用本文:倪永浩.现代二氧化氯制备技术[J].西北轻工业学院学报,2003,21(3):6-9.
作者姓名:倪永浩
作者单位:加拿大新布朗斯维克大学制浆造纸研究中心 加拿大,佛雷德里克顿E3B6C2
摘    要:在现代漂白化学浆制浆厂中,二氧化氯是无元素氯漂白技术(ECF)的关键化学品。二氧化氯的工业化制备过程是基于氯酸盐在强酸性条件下被甲醇或过氧化氢等还原剂还原。作者在本文中综述了几种主要的二氧化氯制备过程的化学反应机理和工艺流程,并讨论了工业化二氧化氯制备过程的最新进展及其相关的效益。

关 键 词:二氧化氯  制备技术  化学反应机理  甲醇  过氧化氢  氯酸盐
文章编号:1000-5811(2003)03-0006-04
修稿时间:2002年4月10日

CHLORINE DIOXIDE MANUFACTURING PROCESSES
NI Yong-hao.CHLORINE DIOXIDE MANUFACTURING PROCESSES[J].Journal of Northwest University of Light Industry,2003,21(3):6-9.
Authors:NI Yong-hao
Abstract:Chlorine dioxide (ClO 2) is the key chemical in a modern ECF bleach plant to produce fully bleached chemical pulps. Chlorine dioxide generation technology is generally based on the reduction of sodium chlorate at a high acidity by chemicals, such as methanol and hydrogen peroxide. In this paper, the chemistry and process layout of the main ClO 2 manufacturing processes were reviewed. Also, the recent development of the commercial process involving the use of co-reducing agents, as well as the associated benefits, was discussed.
Keywords:chemical pulp bleaching  chlorine dioxide generator  mechanism  methanol  hydrogen peroxide
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