Crystalline phase formation in metakaolinite geopolymers activated with NaOH and sodium silicate |
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Authors: | Bo Zhang Kenneth J D MacKenzie and Ian W M Brown |
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Affiliation: | (1) Industrial Research Ltd., P.O. Box 31-310, Lower Hutt, New Zealand |
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Abstract: | The effect of the NaOH content and the presence of sodium silicate activators on the formation of crystalline phases from
metakaolinite-based geopolymers were studied by X-ray powder diffraction (XRD), Rietveld quantitative XRD, solid-state MAS
NMR and SEM in samples synthesized with varying NaOH contents and different curing times at 40 °C. Geopolymers activated with
NaOH alone with Si/Na ratios of 4/4 or less formed the crystalline zeolite Na–A (Na96Al96Si96O384·216H2O), but at ratios >4/4 nanosized crystals of another zeolite (Na6AlSiO4]6·4H2O) were formed. The Si/Na ratio of 4/4 produces a product of greatest crystallinity. The addition of sodium silicate in addition
to NaOH significantly reduces crystallite formation. The network units of all the materials containing NaOH and sodium silicate
are essentially the same, namely, tetrahedral SiO4] units coordinated through four bridging oxygens to four aluminium atoms denoted as Q4 Si(4Al) units]. A templating function of the various silicate units of the sodium silicate molecules is suggested to occur
in geopolymerization, which differs from the reaction route operating when NaOH alone is used as the activator. This templating
function is responsible for the suppression of crystallization and the increase in strength of the geopolymers activated with
sodium silicate. |
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