Adhesive properties of cured epoxide resin containing the intermolecular compound of 2,4-diamino-6-vinyl-s-triazine and isocyanuric acid

The intermolecular compound of 2,4-diamino-6-vinyl-s-triazine and isocyanuric acid was synthesized, and the glass transition temperature and the adhesive properties of the cured epoxide resin containing the above compound were studied. Epoxide reacted with amino groups of 2,4-diamino-6-vinyl-s-triazine and isocyanuric acid at the curing conditions of 150 to 180°C for 60 min and formed the cured compounds. The infrared spectra showed that epoxide reacted with isocyanuric acid in the presence of imidazole compounds and converted to 2-oxazolidinone compound on the curing process. The glass transition temperatures of the cured compounds having isocyanurate and 2-oxazolidinone rings in their structures were higher than that of the epoxide resin cured with imidazole and rise as the curing temperature rises, but fall as 2-oxazolidinone ring content increases in their cured compounds. The tensile shear and peel strengths of the steel and steel bonded with the cured compounds and the cured epoxide resin were measured at 25 and 150°C. The adhesive strengths were improved due to isocyanurate and 2-oxazolidinone rings formed in their cured compounds.