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Structural analysis of deprotonated polyaniline by solid-state 13C N.M.R.
Affiliation:1. Laboratory of Quantum Engineering and Quantum Materials, Guangdong Engineering Technology Research Center of Efficient Green Energy and Environmental Protection Materials, School of Physics and Telecommunication Engineering, South China Normal University, Guangzhou 510006, China;2. School of Science, Jiangnan University, Wuxi, Jiangsu 214122, China;1. Bernal Institute, Department of Chemical Sciences, University of Limerick, Castletroy, Limerick, Ireland;2. National Centre for Sensor Research, School of Chemical Sciences, Dublin City University, Dublin 9, Ireland;3. WestCHEM, Department of Pure and Applied Chemistry, Technology and Innovation Centre, University of Strathclyde, Glasgow G1 1RD, UK
Abstract:The chemical structure of a deprotonated polymer prepared by the oxidation of aniline with ammonium persulfate was analysed with solid-state 13C n.m.r. by using N,N′-diphenyl-p-phenylenediamine, N,N′-diphenyl-p-quinonediimine and N,N-dimethylindoaniline as model compounds. The polymer was found to consist of both amine and benzenoid-quinoid repeating units.
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