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| 氯甲烷在H-ZS M-5催化剂上的催化转化研究 | |
| 引用本文： | 张大治,魏迎旭,许磊,王立刚,常福祥,Bao-lian Su,刘中民. 氯甲烷在H-ZS M-5催化剂上的催化转化研究[J]. 天然气化工, 2006, 31(4): 42-44,48 |
| 作者姓名： | 张大治 魏迎旭 许磊 王立刚 常福祥 Bao-lian Su 刘中民 |
| 作者单位： | 1. 中国科学院大连化学物理研究所,辽宁,大连,116023;中国科学院研究生院,北京,100039 2. 中国科学院大连化学物理研究所,辽宁,大连,116023 3. The University of Namur (FUNDP), B-5000, Namur, Belgium |
| 摘 要： | 研究了氯甲烷在HZSM5分子筛催化剂上的催化转化,产物以高级烷烃和芳烃为主,其分布随反应温度而改变。在400～450℃时,催化剂上结碳量最低,而更高温度的反应产生大量的结碳并导致催化剂迅速失活。FTIR和元素分析表明,产物中的HCl对催化剂的骨架结构和组成没有明显的影响。 |
| 关 键 词： | 氯甲烷 转化 沸石分子筛 H-ZS M-5 烷烃 芳烃 |
| 文章编号： | 1001-9219（2006）04-42-03 |
| 修稿时间： | 2005-10-05 |
The Conversion of Chloromethane Over H-ZSM-5 Zeolite Catalysts |
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| ZHANG Dazhi,WEI Ying-xu,XU Lei,WANG Li-gang,CHANG Fu-xiang,Bao-lian Su,LIU Zhong-min. The Conversion of Chloromethane Over H-ZSM-5 Zeolite Catalysts[J]. Natural Gas Chemical Industry, 2006, 31(4): 42-44,48 | |
| Authors: | ZHANG Dazhi WEI Ying-xu XU Lei WANG Li-gang CHANG Fu-xiang Bao-lian Su LIU Zhong-min |
| Affiliation: | 1. Dalian Institute of Chemical Physics, Chinese Academy of Science, Dalian 116023, china; 2.The University of Namur (FUNDP |
| Abstract: | The catalytic conversion of Chloromethane over H-ZSM-5 zeolite catalysts was studied. The main products were butane. lower parrafins and C_6-C_8 aromatics, and their distribution varied with reaction temperature. In the temperature range of 400 to 450 ℃, the carbon deposition on catalyst was the lowest, over the range the carbon deposition was heavy and caused catalyst activity loss rapidly. FT-IR and element analysis showed that the hydrogen chloride, generated in reaction, has no evident influence on the framework and composition of the catalyst. |
| Keywords: | H-ZSM-5 |
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