| 聚丙烯蜡的接枝改性研究 |
| |
| 引用本文： | 赵科,侯黎黎,刘大壮. 聚丙烯蜡的接枝改性研究[J]. 粘接, 2010, 0(1): 29-32 |
| |
| 作者姓名： | 赵科 侯黎黎 刘大壮 |
| |
| 作者单位： | 郑州大学化工与能源学院,河南,郑州,450002 |
| |
| 基金项目： | 河南省教育厅自然科学基金研究项目(2009A430020) |
| |
| 摘 要： | 用溶液接枝的方法对聚丙烯蜡接枝甲基丙烯酸、苯乙烯（PPW—g—MAA、St）改性，并用红外光谱、化学滴定法对接枝物进行了定性和定量的表征。通过正交实验求出最佳实验条件：T=90℃，nMAA／nSt=2：1，m混合单体／mPPW=0.7：1；讨论了单体物质的量比、单体与聚丙烯蜡质量比、温度对接枝率影响的优先等级。
|
| 关 键 词： | 聚丙烯蜡 甲基丙烯酸 苯乙烯 溶液接枝 接枝率 |
Study on graft modification of polypropylene wax |
| |
| ZHAO Ke,HOU Li-li,LIU Da-zhuang. Study on graft modification of polypropylene wax[J]. Adhesion in China, 2010, 0(1): 29-32 |
| |
| Authors: | ZHAO Ke HOU Li-li LIU Da-zhuang |
| |
| Affiliation: | School of Chemical and Energy Engineering/a>;Zhengzhou University/a>;Zhengzhou/a>;Henan 450002/a>;China |
| |
| Abstract: | The solution grafting method was used to make polypropylene wax grafted methylacrylic acid and styrene（（PPW-g- MAA, St）. The infrared spectrometry and chemical titration were also used for qualitative and quantitative characterization of the graft. Using the orthogonal experiments the best experimental condition was obtained：T=90 ℃,nMAA/nSt=2 ： 1, m=ix/mppw=0.7 ： 1; The priority-rating of effects of molar ratio of monomers , weight ratio of monomers and polypropylene wax and temperature on grafting rate was discussed.. |
| |
| Keywords: | polypropylene wax methylacrylic acid styrene solution grafting grafting rate |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
