A screen-printed Ce0.8Sm0.2O1.9 film solid oxide fuel cell with a Ba0.5Sr0.5Co0.8Fe0.2O3−δ cathode |
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Authors: | Yaohui Zhang Xiqiang Huang Zhe Lu Zhiguo Liu Xiaodong Ge Jiahuan Xu Xianshuang Xin Xueqing Sha Wenhui Su |
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Affiliation: | aCenter for Condensed Matter Science and Technology, Harbin Institute of Technology, Harbin 150001, People's Republic of China bDepartment of Condensed Matter Physics, Jilin University, Changchun 130022, People's Republic of China cInternational Center for Materials Physics, Academia, Shenyang 110015, People's Republic of China |
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Abstract: | Screen-printing technology was developed to fabricate Ce0.8Sm0.2O1.9 (SDC) electrolyte films onto porous NiO–SDC green anode substrates. After sintering at 1400 °C for 4 h, a gas-tight SDC film with a thickness of 12 μm was obtained. A novel cathode material of Ba0.5Sr0.5Co0.8Fe0.2O3?δ was subsequently applied onto the sintered SDC electrolyte film also by screen-printing and sintered at 970 °C for 3 h to get a single cell. A fuel cell of Ni–SDC/SDC (12 μm)/Ba0.5Sr0.5Co0.8Fe0.2O3?δ provides the maximum power densities of 1280, 1080, 670, 370, 180 and 73 mW cm?2 at 650, 600, 555, 505, 455 and 405 °C, respectively, using hydrogen as fuel and stationary air as oxidant. When dry methane was used as fuel, the maximum power densities are 876, 568, 346 and 114 mW cm?2 at 650, 600, 555 and 505 °C, respectively. The present fuel cell shows excellent performance at lowered temperatures. |
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Keywords: | Solid oxide fuel cells Screen-printing Electrolyte films Ce0 8Sm0 2O1 9 Ba0 5Sr0 5Co0 8Fe0 2O3?δ |
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