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A screen-printed Ce0.8Sm0.2O1.9 film solid oxide fuel cell with a Ba0.5Sr0.5Co0.8Fe0.2O3−δ cathode
Authors:Yaohui Zhang  Xiqiang Huang  Zhe Lu  Zhiguo Liu  Xiaodong Ge  Jiahuan Xu  Xianshuang Xin  Xueqing Sha  Wenhui Su  
Affiliation:

aCenter for Condensed Matter Science and Technology, Harbin Institute of Technology, Harbin 150001, People's Republic of China

bDepartment of Condensed Matter Physics, Jilin University, Changchun 130022, People's Republic of China

cInternational Center for Materials Physics, Academia, Shenyang 110015, People's Republic of China

Abstract:Screen-printing technology was developed to fabricate Ce0.8Sm0.2O1.9 (SDC) electrolyte films onto porous NiO–SDC green anode substrates. After sintering at 1400 °C for 4 h, a gas-tight SDC film with a thickness of 12 μm was obtained. A novel cathode material of Ba0.5Sr0.5Co0.8Fe0.2O3?δ was subsequently applied onto the sintered SDC electrolyte film also by screen-printing and sintered at 970 °C for 3 h to get a single cell. A fuel cell of Ni–SDC/SDC (12 μm)/Ba0.5Sr0.5Co0.8Fe0.2O3?δ provides the maximum power densities of 1280, 1080, 670, 370, 180 and 73 mW cm?2 at 650, 600, 555, 505, 455 and 405 °C, respectively, using hydrogen as fuel and stationary air as oxidant. When dry methane was used as fuel, the maximum power densities are 876, 568, 346 and 114 mW cm?2 at 650, 600, 555 and 505 °C, respectively. The present fuel cell shows excellent performance at lowered temperatures.
Keywords:Solid oxide fuel cells  Screen-printing  Electrolyte films  Ce0  8Sm0  2O1  9  Ba0  5Sr0  5Co0  8Fe0  2O3?δ
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