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A Highly Efficient Palladium‐Catalyzed One‐Pot Synthesis of Unsymmetrical Aryl Alkyl Thioethers under Mild Conditions in Water |
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| Authors: | Liang Wang Wei‐You Zhou Sheng‐Chun Chen Ming‐Yang He Qun Chen |
| Abstract: | A palladium‐catalyzed, one‐pot synthesis of unsymmetrical aryl alkyl thioethers involving aryl halides (aryl bromides and chlorides), thiourea and alkyl bromides has been realized under mild conditions (room temperature to 50 °C) in water with polyoxyethanyl α‐tocopheryl sebacate (PTS) as amphiphile. The PTS/water could be recycled in up to eight runs without an obvious change in its activity. |
| Keywords: | aryl halides micellar catalysis polyoxyethanyl α ‐tocopheryl sebacate (PTS)/water thiourea unsymmetrical aryl alkyl thioethers |