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Asymmetric Hydrosilane Reduction of Ketones Catalyzed by an Iridium Complex Bearing a Hydroxyamide‐Functionalized NHC Ligand |
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| Authors: | Shun Kawabata Hiromu Tokura Hiroyuki Chiyojima Masaki Okamoto Satoshi Sakaguchi |
| Abstract: | An enantioselective hydrosilylation of prochiral ketones was achieved by using a catalytic amount of the readily accessible and air‐ and moisture‐stable iridium complex IrCl(cod)(NHC)] at room temperature. |
| Keywords: | asymmetric catalysis carbene ligands hydrosilylation iridium ketones |