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Deposition of Gold Particles on Mesoporous Catalyst Supports by Sonochemical Method, and their Catalytic Performance for CO Oxidation
Authors:Nina Perkas  Ziyi Zhong  Judit Grinblat  Aharon Gedanken
Affiliation:(1) Department of Chemistry and Kanbar Laboratory for Nanomaterials, Bar-Ilan University Center for Advanced Materials and Nanotechnology, Bar-Ilan University, Ramat-Gan, 52900, Israel;(2) Institute of Chemical and Engineering and Sciences, 1 Pesek Road, Jurong Island, 627833, Singapore
Abstract:Supported gold catalysts on the mesoporous (MSP) metal oxides were prepared by a one-step, ultrasound-assisted reduction method, and characterized by XRD, HRTEM, EDX, BET, and XPS analysis. Their catalytic activities were examined in the oxidation of CO. Compared to the Au/Fe2O3(MSP) catalyst, the Au/TiO2(MSP) and Au/Fe2O3-TiO2(MSP) catalysts exhibited higher catalytic activity in the oxidation of CO at low temperatures. The high catalytic activity of Au/TiO2(MSP) was attributed to the metallic state of the gold nanoparticles, their small size (2–2.5 nm), and their high dispersion on the catalyst support.
Keywords:Sonochemical reduction  Gold  Mesoporous support  CO oxidation
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