| 蝎型聚吡唑硼酸盐碱金属配合物的合成、晶体结构及性质 |
| |
| 引用本文： | 姚强,赵海燕,万丽娟,邢永恒.蝎型聚吡唑硼酸盐碱金属配合物的合成、晶体结构及性质[J].吉林化工学院学报,2011,28(3):8-12. |
| |
| 作者姓名： | 姚强 赵海燕 万丽娟 邢永恒 |
| |
| 作者单位： | 辽宁师范大学,化学化工学院,辽宁,大连,116029 |
| |
| 基金项目： | 国家自然科学基金资助项目 |
| |
| 摘 要： | 设计合成了一种新型的蝎型聚吡唑硼酸盐碱金属配合物K(H2O)B(pz)4(]1).通过元素分析,红外光谱和粉末XRD对配合物进行了表征,并用X-Ray测定了它的晶体结构.所得晶体学参数为:a=1.506 6(3)nmb,=0.867 13(17)nmc,=2.419 2(5)nm,β=105.77(3)°,V=3.041 6(10)nm3,Z=8,Dcalc=1.473 g.cm-1,μ=3.66 cm-1,F(000)=1 400,晶体属单斜晶系,空间群为C 2/c.配合物分子间经由C—H…O氢键连接无限延伸成二维网状结构.
|
| 关 键 词： | 聚吡唑硼酸盐 合成 晶体结构 氢键 |
Synthesis,crystal structure and properties of scorpionates poly(pyrazolyl)borate complex |
| |
| YAO Qiang,ZHAO Hai-yan,WAN Li-juan,XING Yong-heng.Synthesis,crystal structure and properties of scorpionates poly(pyrazolyl)borate complex[J].Journal of Jilin Institute of Chemical Technology,2011,28(3):8-12. |
| |
| Authors: | YAO Qiang ZHAO Hai-yan WAN Li-juan XING Yong-heng |
| |
| Affiliation: | YAO Qiang,ZHAO Hai-yan,WAN Li-juan,XING Yong-heng (College of Chemistry and Chemical Engineering,Liaoning Normal University,Dalian 116029,China) |
| |
| Abstract: | A new scorpionates poly（pyrazolyl）borate complex,K（H 2O）B（pz） 4]（1） was designed and synthesized.It was characterized by element analysis,IR spectra,XRD and single crystal X ray diffraction.Its unit cell parameters are as follows： a =15.066（3）nm,b =8.671 3（17）nm,c =24.192（5）nm,β =105.77（3）nm,V = 3041.6（10）nm 3,Z = 8,D calc =1.473 g·cm-1,μ = 3.66 cm-1,F（000） = 1 400.The crystalline belongs to monoclinic with space group C 2/c.The molecules are connected through the hydrogen bonds of C—H…O to generate a 2D network on the ab plane. |
| |
| Keywords: | poly(pyrazolyl)borate synthesis crystal structure hydrogen bonds |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
