Photoelectrochemical analysis of the effects of pH and sulfate ions on the structure and the composition of the passive film formed on Fe-20Cr-15Ni alloy |
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Authors: | HeeJin Jang ChanJin Park HyukSang Kwon |
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Affiliation: | (1) Dept. of Metallurgical Engineering, Chosun University, 375, Seoseok-dong, Dong-gu, Gwangju, 501-759, Korea;(2) School of Materials Science and Engineering, Chonnam National University, 300, Yongbong-dong, Buk-gu, Gwangju, 500-757, Korea;(3) Dept. of Materials Science and Engineering, Korea Advanced Institute of Science and Technology, 373-1, Guseong-dong, Yuseong-gu, Daejeon, 305-701, Korea |
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Abstract: | The effects of pH and sulfate ions on the structure and compositions of the passive film formed on Fe-20Cr- 15Ni were examined
using a photoelectrochemical technique and Mott-Schottky analysis. The photocurrent spectra for the passive film formed on
Fe-20Cr-15Ni in the buffer solutions are composed of two spectral components, one of which is generated from Cr-substituted
γ-Fe2O3 and the other of which is generated from NiO. However, the passive film formed in sulfate solutions showed only the photocurrent
spectrum of Cr-substituted γ-Fe2O3, suggesting that the formation of NiO in the passive film is suppressed because of a severe selective dissolution of Ni in
the presence of sulfate ions. Mott-Schottky plots confirmed that the base structure of the passive film on Fe-20Cr-15Ni is
n-type (Cr, Ni)-substituted γ-Fe2O3 regardless of solution pH and sulfate ions. The photocurrent intensity, flat band potential, and donor density for the passive
film varied depending on the solution pH or the presence of sulfate ions in the solution, due primarily to the Cr enrichment
in the film caused by the preferential dissolution of Fe and Ni that is more appreciable in highly acidic solutions containing
sulfate ions. |
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Keywords: | stainless steels passive film semiconducting property |
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