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Synthesis of boron nitride
Authors:A K Basu  J Mukerji
Affiliation:(1) Central Glass and Ceramic Research Institute, 700 032 Jadavpur, Calcutta, India
Abstract:The authors examine the boric oxide—ammonia route with special stress on the yield and composition of the intermediate addition compound (BN) x (B2O3) y (NH3) z . It has been concluded that B2O3 and NH3 present in the addition compound formed between 350°C and 900°C cannot be further reacted to convert the B2O3 into BN and the BN yield remains at around 66%. A formula (BN)12·7(B2O3)7·5NH3 has been suggested for the addition compound.
Keywords:Boron nitride  synthesis  addition compound
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