Temperature treatment of nano-scaled barium titanate filler to improve the dielectric properties of high-k polymer based composites |
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Authors: | Benedikt Schumacher,Holger Geß wein,Jü rgen Hauß elt,Thomas Hanemann |
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Affiliation: | Karlsruhe Institute of Technology, KIT-Campus North, P.O. Box 3640, 76021 Karlsruhe, Germany |
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Abstract: | A commercially available nano-scaled barium titanate powder was compounded with a polyester-styrene reactive resin to create a high-k polymer-composite material. The influence of a temperature treatment on the filler was examined for treatment temperatures between 500 and 1200 °C. As a result grain and particle growth as well as lattice relaxation was induced into the powder particles. The resulting composite permittivity rises from 9.2 to 25.0 (at room temperature, 1 kHz, filler load 60 wt%/∼22 vol%) and the dielectric loss factor drops to values below 0.005 as a result of this treatment. The changes in lattice structure, powder morphology and composite viscosity were determined by XRD, SEM, BET, He-pycnometry and rheology measurements. The temperature dependency of the dielectric properties of the pure polymer and the composite were measured between −60 and 70 °C. The temperature dependency of the polymer matrix is superimposed with the temperature characteristic of the BaTiO3. |
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Keywords: | Barium titanate Polymer composite Dielectric properties |
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