Synthesis and X-ray crystal structure determination of monomeric cis-Pd(2,2′-bipyridine)(NO3)2 |
| |
| Authors: | Rafael A Adrian Shourong Zhu Kevin K Klausmeyer Judith A Walmsley |
| |
| Affiliation: | aDepartment of Chemistry, The University of Texas at San Antonio, San Antonio, TX 78249, USA;bDepartment of Chemistry and Biochemistry, Baylor University, Waco, TX 76706, USA |
| |
| Abstract: | Complex cis-Pd(2,2′-bipyridine)(NO3)2 was synthesized by the reaction of cis-Pd(2,2′-bipyridine)Cl2 with AgNO3 in water and crystallized by vapor diffusion of diethyl ether into an acetonitrile solution of the complex. The crystal structure obtained shows that each of the two nitrate ligands are coordinated through oxygen atoms to the Pd(2,2′-bipyridine)2+ center in unidentate fashion. IR and 1H NMR spectral data were also obtained. |
| |
| Keywords: | Palladium Nitrato complex Bipyridine Monomer 2 2′ -Bipyridine |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
