| 水热法制备质子交换膜燃料电池阴极Pt/C催化剂 |
| |
| 引用本文： | 温恒,秦怡红,李文良. 水热法制备质子交换膜燃料电池阴极Pt/C催化剂[J]. 电源技术, 2010, 34(2) |
| |
| 作者姓名： | 温恒 秦怡红 李文良 |
| |
| 作者单位： | 1. 中南大学,冶金科学与工程学院,湖南,长沙,410083
2. 深圳市豪鹏科技有限公司,广东,深圳,518111 |
| |
| 摘 要： | 采用硫代乙酰胺(TAA)为沉淀剂,水热法合成40%Pt/C质子交换膜燃料电池阴极催化剂,通过X射线衍射(XRD)和透射电镜(TEM)考察了Pt/C催化剂的物理性能,并利用循环伏安法(CV)分析了催化剂的电化学活性,采用旋转圆盘电极(RDE)评价了催化剂的氧还原催化活性。实验表明水热硫化物沉淀法合成催化剂受反应pH值、氯铂酸与沉淀剂硫代乙酰胺的配比、H2热处理等制备条件的影响,制得的Pt/C催化剂粒径小(平均粒径3nm左右)并且分布均匀,催化性能较好。
|
| 关 键 词： | 质子交换膜燃料电池 Pt/C催化剂 水热法 硫代乙酰胺 氧还原反应 |
Pt/C catalyst prepared by hydrothermal method for PEMFC |
| |
| WEN Heng,QIN Yi-hong,LI Wen-liang. Pt/C catalyst prepared by hydrothermal method for PEMFC[J]. Chinese Journal of Power Sources, 2010, 34(2) |
| |
| Authors: | WEN Heng QIN Yi-hong LI Wen-liang |
| |
| Affiliation: | 1. College of Metallurgy Science and Engineering;Central South University;Changsha Hunan 410083;China;2. Shenzhen High Power Technology Co. Ltd.;Shenzhen Guangdong 518111;China |
| |
| Abstract: | 40% Pt/C electrocatalysts for PEMFC were prepared by hydrothermal method with thioacetamide(TAA) as precipitator, the physical performance of Pt/C catalysts were characterized by TEM, and XRD, the electrochemical activity of the catalyst were analyzed by cyclic voltammetry(CV), and the activity towards oxygen electro reduction was studied with the rotating disk electrode (RDE). The test results show that Pt/C catalysts are affected by preparation conditions, such as pH in the solution, the atom ratio of chl... |
| |
| Keywords: | proton exchange membrane fuel cells Pt/C catalyst hydrothermal method thioacetamide oxygen reduction reaction |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
