| 含金属氢化物的p(BAMO-AMMO)基推进剂能量特性 |
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| 引用本文： | 裴江峰,;赵风起,;焦建设,;李猛,;徐司雨,;陈俊波.含金属氢化物的p(BAMO-AMMO)基推进剂能量特性[J].爆破器材,2014(4):11-15. |
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| 作者姓名： | 裴江峰 ;赵风起 ;焦建设 ;李猛 ;徐司雨 ;陈俊波 |
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| 作者单位： | [1]西安近代化学研究所燃烧与爆炸技术重点实验室,陕西西安710065; [2]炮兵防空兵装备技术研究所,北京100012 |
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| 基金项目： | 国家自然科学基金（No.2173163） |
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| 摘 要： | 为了考察金属氢化物(MH)对3,3-二叠氮甲基氧杂环丁烷(BAMO)与3-甲基-3-叠氮甲氧基氧杂环丁烷(AMMO)嵌段共聚物p(BAMO-AMMO)基推进剂的能量特性影响,设计了高氯酸铵(AP)、MH、p(BAMO-AMMO)组成的三组元推进剂配方体系,计算了用不同的MH逐步取代AP时的标准理论比冲变化规律,同时计算并比较了含六硝基六氮杂异伍兹烷(CL-20)的四组元p(BAMO-AMMO)基推进剂配方体系的标准理论比冲。研究发现AlH3对提升推进剂能量效果最为明显,以其取代25%(质量分数)AP的三组元推进剂和取代20%(质量分数)AP的四组元推进剂能量分别达到最高值(2764.9 N·s/kg和2829.3 N·s/kg);当AlH3完全取代某实际推进剂配方中的Al时,推进剂的标准理论比冲提高了5.1%。
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| 关 键 词： | 金属氢化物 BAMO-AMMO共聚物 推进剂 能量特性 理论计算 |
Energetic Characteristics of BAMO-AMMO Based Propellants Containing Different Metal Hydride |
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| Affiliation: | PEI Jiangfeng, ZHAO Fengqi, JIAO Jianshe, LI Meng, XU Siyu CHEN Junbo (1.Science and Technology on Combustion and Explosion Laboratory, Xi＇an Modern Chemistry Research Institute ( Shaanxi Xi＇an, 710065 2.Equipment and Technologies Research Institute of FA and ADA ( Beijing, 100012)) |
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| Abstract: | Formulas consisting of AP/MH/p（BAMO-AMMO） propellant was designed to study the effect of metal hydride （MH） on energetic characteristics of propellants based on copolymer of 3,3＇-bis（azidomethyl） oxetane （BAMO） and 3-azidomethyl-3- methyloxetane （AMMO）. Through gradual substitution of MH for AP, the effect laws of MH to the theoretical specific impulse （Isp） of AP/MH/p（BAMO-AMMO） propellants was obtained. Results show that A1H3 was the most effective material for increasing the /sP of propellents. The Isp of AP/MH/p （ BAMO-AMMO ） propellant is up to 2764.9 N · s/kg when 25% AP is replaced by A1H3 , and the/sP of CL-20/AP/MH/p（BAMO-AMMO） propeUant is up to 2829.3 N · s/kg when 20% AP is replaced. When all AI is redaced by A1H3 , the Isp of a propellant containing p（ BAMO- AMMO） is improved by 5.1%. |
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| Keywords: | metal hydride （MH） p（BAMO-AMMO） propellants energy characteristics theoretical calculation |
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