| 交替微层结构PPCB/PP导电复合材料的结构与性能EI |
| |
| 引用本文： | 杜海兵,顾思贾,刘峰.交替微层结构PPCB/PP导电复合材料的结构与性能EI[J].高分子材料科学与工程,2009(1):41-44. |
| |
| 作者姓名： | 杜海兵 顾思贾 刘峰 |
| |
| 作者单位： | 超细材料制备与应用教育部重点实验室;华东理工大学材料科学与工程学院;超细材料制备与应用教育部重点实验室华;东理工大学材料科学与工程学院; |
| |
| 基金项目： | 国家自然科学基金资助项目 |
| |
| 摘 要： | 利用自主设计的微层共挤出设备,制备了具有交替微层结构的炭黑填充聚丙烯/聚丙烯(PPCB/PP)导电复合材料。PPCB层和PP层均为连续相,炭黑仅选择性分散在PPCB层内,形成一种特殊的双逾渗现象。电性能测试表明,微层共挤出技术可显著降低微层PPCB/PP复合材料的逾渗阈值和电阻率,其导电性能与材料层数相关。此外,微层共挤出方法能明显改善材料的韧性。
|
| 关 键 词： | 聚丙烯 炭黑 导电复合材料 微层共挤出 |
Synthesis and Properties of Novel Branched Conjugated Polymer |
| |
| DU Hai-bing,GU Si-jia,LIU Feng.Synthesis and Properties of Novel Branched Conjugated Polymer[J].Polymer Materials Science & Engineering,2009(1):41-44. |
| |
| Authors: | DU Hai-bing GU Si-jia LIU Feng |
| |
| Affiliation: | School of Materials Science and Engineering.East China University of Science and Technology.Shanghai 200237;China |
| |
| Abstract: | The branched conjugated polymer of Polyfluorene/ Poly(p-Phenylene vinylenes)(PFO/PPV) was synthesized based on"A2+B2+B3"approach method containing triphenyamine as its core through Heck condensation coupling.The structure of the result polymer was characterized by FT-IR,1H-NMR,Elemental Analysis ,GPC.The branched polymer has good solubility and thermal stability.The optical and fluorescence quenching properties in dilute solution of the polymer was revealed by UV,PL Spectroscopy.It shows PL quenching sensit... |
| |
| Keywords: | branched conjugated polymer Heck condensation fluorescence quenching |
| 本文献已被 CNKI 维普 等数据库收录！ |
