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染料敏化太阳能电池光阳极TiO_2致密膜的制备
引用本文:刘显卿,胡志强,黄德锋,秦颖,杨冬雪,殷克剑.染料敏化太阳能电池光阳极TiO_2致密膜的制备[J].大连工业大学学报,2013(1):36-38.
作者姓名:刘显卿  胡志强  黄德锋  秦颖  杨冬雪  殷克剑
作者单位:大连工业大学新能源材料研究所
基金项目:国家高技术研究发展计划(863计划)项目(2006AA05Z417);大连市科技平台建设项目(2010-354)
摘    要:用溶胶-凝胶法在染料敏化太阳能电池的FTO导电玻璃与多孔薄膜之间制备了一层TiO2致密膜,采用AFM、XRD、UV-Vis以及接触角测定仪等对其进行表征。结果表明,制备的薄膜结构致密、透明,晶粒细小均匀;水接触角从FTO表面的54.425°下降到致密膜表面的33.763°,有利印刷浆料润湿结合;对比实验证实了TiO2致密膜的引入,隔离了液体电解质与FTO导电玻璃的直接接触,减小电池的暗电流,电池的电流密度及光电转化效率分别提高了17.7%和22.4%。

关 键 词:染料敏化太阳能电池(DSSC)  致密膜  光电转化效率

Preparation of DSSC photoanode TiO2 density film
LIU Xianqing,HU Zhiqiang,HUANG Defeng,QIN Ying,YANG Dongxue,YIN Kejian.Preparation of DSSC photoanode TiO2 density film[J].Journal of Dalian Dalian Polytechnic University,2013(1):36-38.
Authors:LIU Xianqing  HU Zhiqiang  HUANG Defeng  QIN Ying  YANG Dongxue  YIN Kejian
Affiliation:Institute of New Energy Material,Dalian Polytechnic University,Dalian 116034,China
Abstract:The TiO_2 density film was prepared by the sol-gel method between the Fluorine Tin Oxide(FTO) Glass and multiporous film in the DSSC and characterized by AFM,XRD,UV-Vis and contact angle measuring instrument.The results showed that the grain size of the TiO_2 was fine,the film was dense and transparent,the water contact angle decreased from 54.425° to 33.763° on FTO.Compared to the DSSC with no coating TiO_2 density film,the introduction of the density film avoided the contact of electrolyte with FTO directly which decreased the dark current,the photoelectric conversion efficiency and short-circuit photocurrent increased by 17.7%,22.4%,respectively.
Keywords:dye-sensitized solar cells(DSSC)  density film  photoelectric conversion efficiency
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