| 电铝热还原电炉钛渣制备Ti-Al-xFe-ySi合金 |
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| 引用本文： | 李军,鲁雄刚,杨绍利,马兰,吴恩辉,侯静,李重河,王涛,李彬彬.电铝热还原电炉钛渣制备Ti-Al-xFe-ySi合金[J].有色金属(冶炼部分),2017(8):25-29. |
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| 作者姓名： | 李军 鲁雄刚 杨绍利 马兰 吴恩辉 侯静 李重河 王涛 李彬彬 |
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| 作者单位： | 上海大学 省部共建高品质特殊钢冶金与制备国家重点实验室,上海大学 省部共建高品质特殊钢冶金与制备国家重点实验室,攀枝花学院,攀枝花学院,攀枝花学院,攀枝花学院,上海大学 省部共建高品质特殊钢冶金与制备国家重点实验室,攀枝花学院,上海大学 省部共建高品质特殊钢冶金与制备国家重点实验室;攀枝花学院 |
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| 基金项目： | 国家重点基础发展计划项目（2014CB643403）；四川省科技支撑计划项目（2013GC0146）；攀枝花市科技计划项目(2014CY-G-5) |
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| 摘 要： | 利用攀枝花产的电炉钛渣铝热还原一步合成Ti-Al-xFe-ySi多元合金,探索CaO对渣金分离、合金收率及钛收率的影响。当CaO/Al=1.1时,制备的熔渣主要生成了低熔点Al_2O_3·CaO和7Al_2O_3·12CaO相,渣金分离效果最好。合金收率达到62%,Ti收率达到92%,合金中氧含量仅为1.32%。制备的合金主要物相为TiAl_3、TiAl相,而渣中还原出来的Fe替代了TiAl3中的部分Ti形成了Al_3Ti_(0.75)Fe_(0.25)物相,而Si主要与合金中的Ti结合生成了Ti5Si3相,合金中还含有少量的碳与TiAl和TiSi相形成了Ti_3SiC_2和Ti_2AlC新相。
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| 关 键 词： | 电炉钛渣 电铝热还原 Ti-Al-xFe-ySi多元合金 |
| 收稿时间： | 2017/3/24 0:00:00 |
| 修稿时间： | 2017/3/28 0:00:00 |
Preparation of Ti-Al-xFe-ySi Alloy from Electro-titanium Slag by Electro-Aluminothermic Reduction |
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| LI Jun,LU Xiong-Gang,YANG Shao-Li,Ma Lan,WU En-Hui,HOU Jing,LI Chong-He,Wang Tao and Li Bin-Bin.Preparation of Ti-Al-xFe-ySi Alloy from Electro-titanium Slag by Electro-Aluminothermic Reduction[J].Nonferrous Metals(Extractive Metallurgy),2017(8):25-29. |
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| Authors: | LI Jun LU Xiong-Gang YANG Shao-Li Ma Lan WU En-Hui HOU Jing LI Chong-He Wang Tao and Li Bin-Bin |
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| Affiliation: | Shanghai University,National key laboratory of high-quality special steel metallurgy and preparation by the province and the ministry,,,,,,,, |
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| Abstract: | Ti-Al-xFe-ySi alloy was synthesized from electro-titanium slag in Panzhihua by electro-aluminothermic reduction. Effect of CaO addition on slag-gold separation, alloy yield, and titanium yield was investigated. With CaO/Al of 1.1, low melting point phases such as Al2O3?CaO and 7Al2O3?12CaO are mainly produced from reduction slag, and yield of alloy and Ti is 62% and 92% respectively with oxygen content in alloy of 1.32%. Main phase of alloy is composed of TiAl3 and TiAl, Fe in slag replaces Ti in TiAl3 to form Al3Ti0.75Fe0.25, and Si is mainly combined with Ti in alloy to form Ti5Si3. Small amount of C in alloy combines with TiAl and TiSi to form new phase of Ti3SiC2 and Ti2AlC. |
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| Keywords: | electro-titanium slag electro-aluminothermic reduction Ti-Al-xFe-ySi alloy |
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