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Environmentally assisted “in-bulk” steel degradation of long term service gas trunkline
Authors:H Nykyforchyn  E Lunarska  OT Tsyrulnyk  K Nikiforov  ME Genarro  G Gabetta
Affiliation:1. Karpenko Physico-Mechanical Institute of the NAS of Ukraine, Naukova Str. 5, 79601 Lviv, Ukraine;2. Institute of Physical Chemistry of the Polish Academy of Sciences, Kasprzaka Str. 44/52, 01-224 Warszawa, Poland;3. Venezia Tecnologie S.p.A., Via Delle Industrie, 39-30175 Porto Marghera, Venezia, Italy;4. Eni, Via Emilia 1, 20097 San Donato Milanese (Milano), Italy
Abstract:Comparison of mechanical (characteristics of strength, reduction of area and elongation, impact strength, hardness, fracture toughness), corrosion-mechanical (stress corrosion cracking in the artificial brine and hydrogen embrittlement) properties and parameters of hydrogen behaviour in the X52 steel in as-received state and after long term service are presented in the paper. The analysis of a change of the mentioned characteristics together with the results of hydrogen permeation and vacuum hydrogen extraction measurements indicate considerable “in-bulk” material degradation of trunk pipeline steel after long term service and essential role of hydrogen in these processes. The measurements of the internal friction have shown the enhancement of grain boundary relaxation, which has been associated with the formation of defects at the grain boundaries. Two stages of the “in-bulk” degradation of steel in the course of its long term exploitation in the pipe lines have been postulated: (1) the deformation aging and (2) the formation and evolution of microdefects.
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