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红外光谱法测定邻苯二甲酸混合酯中酯基碳数
引用本文:王继有,杨晓佳.红外光谱法测定邻苯二甲酸混合酯中酯基碳数[J].辽宁石油化工大学学报,1999,19(2).
作者姓名:王继有  杨晓佳
作者单位:辽宁省化工研究院分析室,辽宁大连,116023
摘    要:邻苯二甲酸混合酯的定性分析是一项较困难的工作,主要问题在于酯基中的碳数为一种分布或几种不同碳数的混合体,如采用通常的分离测定很难实现的。利用红外光谱法,通过红外吸收强度差值来测定邻苯二甲酸混合酯中单酯基的平均碳数。并利用此法,测得某厂进口增塑剂邻苯二甲酸混合酸的平均碳数为14,得到了一个较满意的结果

关 键 词:邻苯二甲酸二酯  增塑剂  吸收强度差值
修稿时间:1999-03-19

Determination of Average Carbon Number in Monester Alkyl of Mi xture Ester Phthalate by IR
Wang Jiyou,Yang Xiaojia.Determination of Average Carbon Number in Monester Alkyl of Mi xture Ester Phthalate by IR[J].Journal of Liaoning University of Petroleum & Chemical Technology,1999,19(2).
Authors:Wang Jiyou  Yang Xiaojia
Abstract:It is diffcult to determinate mixture ester phthalate qualitatively , and the problem is that the carbon number of mixture ester phthalate is a mixture of several carbon numbers or in a distrbution. It is not available to determinate average carbon number by separation. In this paper, the good result was obtained to determine average carbon number in monester alkyl of mixture ester phthalate by the difference of infrared absorption intensity. Average carbon number of 14 in monester alkyl in a chemical plants plasticizer has been obtained by this method.
Keywords:Diester phthalate  Plasticizer  Difference of infrared absorption intensity
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