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用硅烷封端的湿固化聚氨酯热熔胶的研制
引用本文:唐礼道,杨建军,张建安,吴庆云,吴明元.用硅烷封端的湿固化聚氨酯热熔胶的研制[J].中国胶粘剂,2007,16(4):37-39.
作者姓名:唐礼道  杨建军  张建安  吴庆云  吴明元
作者单位:安徽大学化学化工学院与安徽省绿色高分子材料重点实验室,安徽,合肥,230039
摘    要:通过聚氨酯预聚体法合成出硅烷KH-550封端的聚氨酯热熔胶(SPUR),并制备了一系列不同封端率的硅烷化聚氨酯热熔胶。通过红外光谱、表面接触角等检测了SPUR的结构和性能,研究了硅烷对聚氨酯热熔胶粘接性能的影响。结果表明:硅烷提高了SPUR在粘接面的浸润和对铝片的粘接性能,当KH-550封端率达到15%时,粘接性能最佳。

关 键 词:硅烷  湿固化  聚氨酯热熔胶  封端率
文章编号:1004-2849(2007)04-0037-03
修稿时间:2007-01-31

The research of moisture-curable polyurethane hot melt adhesives with silane ending
TANG Li-dao,YANG Jian-jun,ZHANG Jian-an,WU Qing-yun,WU Ming-yuan.The research of moisture-curable polyurethane hot melt adhesives with silane ending[J].China Adhesives,2007,16(4):37-39.
Authors:TANG Li-dao  YANG Jian-jun  ZHANG Jian-an  WU Qing-yun  WU Ming-yuan
Abstract:Silylated hot melt moisture cured polyurethane adhesive(SPUR)was prepared with KH-550,and a series of polymer was synthesized with different silane ending ratio. The configuration and performance of SPUR were reviewed by FT-IR, contact angle etc. The influence of SPUR's bonding performance to Al was researched. Testing showed that KH-550 changed the surface energy of SPUR,improved the soakage to surface of materials, and bonding is improved greatly. When the silane ending ratio is 15%,adhesive strength is best.
Keywords:silane  moisture cured  hot melt polyurethane adhesives  ending ratio
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