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Silicotungstic acid stabilized Pt–Ru nanoparticles supported on carbon nanofibers electrodes for methanol oxidation
Authors:T Maiyalagan
Affiliation:Department of Chemistry, School of Science and Humanities, VIT University, Vellore 632014, India
Abstract:Silicotungstic acid stabilized Pt–Ru nanoparticles supported on Functionalized Carbon Nanofibers have been prepared by a microwave-assisted polyol process. The samples were characterized by XRD, SEM and TEM analysis. The electro-catalytic activities of the prepared composites (20% Pt–Ru/STA–CNF) were examined by using Cyclic Voltammetry (CV) for oxidation of methanol. The electro-catalytic activity of the carbon nanofiber based composite (20% Pt–Ru/STA–CNF) electrode for methanol oxidation showed better performance than that of commercially available Johnson Mathey 20% Pt–Ru/C and 20% Pt–Ru/STA–C catalyst. The results imply that carbon nanofiber based STA composite electrodes are excellent potential candidates for application in direct methanol fuel cells.
Keywords:Polyoxometalates  Pt&ndash  Ru  Carbon nanofibers  Electrocatalyst  Methanol oxidation  Fuel cells
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